“…Cross plots of diagnostic molecular ratios are widely used to distinguish PAHs sourced from fossil fuels versus burn products (Lima et al., 2005; Tobiszewski & Namieśnik, 2012; Yunker et al., 2002). In paleofire studies, these cross‐plots are used to screen sediments for pristine pyrogenic samples (Callegaro et al., 2018; Denis et al., 2012; Hossain et al., 2013). However, due to variable end‐member patterns (Guillon et al., 2013; Yunker et al., 2002), and the influence of degradation or transport processes, simple ratio‐based methods become less diagnostic (Stogiannidis & Laane, 2015) (Figure ).…”