2003
DOI: 10.1016/s0022-328x(03)00321-8
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First heterobimetallic complexes of phosphocavitands

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Cited by 8 publications
(7 citation statements)
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“…Later, anionic complexes have been prepared on the basis of amidophosphitocavitands and copper chloride 40 or silver bromide. 41 Note that the ligand remains fully symmetrical in any of the above-mentioned metal complexes.…”
Section: Reactivity Of P(iii)-phosphocavitandsmentioning
confidence: 99%
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“…Later, anionic complexes have been prepared on the basis of amidophosphitocavitands and copper chloride 40 or silver bromide. 41 Note that the ligand remains fully symmetrical in any of the above-mentioned metal complexes.…”
Section: Reactivity Of P(iii)-phosphocavitandsmentioning
confidence: 99%
“…This spectral pattern points to a structural difference between the phosphocin rings. An X-ray diffraction study of the rhodium complex 16 (R ) Me, X ) Oi-Pr) 42 showed that three phosphocin rings have a chair-boat conformation typical of symmetrical phosphocavitands 9,[16][17][18][19][20]31,[37][38][39][40][41] and the fourth one is in a boat conformation; the rhodium fragments are directed equatorially, while the isopropoxy groups have an axial orientation. Thus, the introduction of the bulky rhodium-containing fragments to four phosphorus atoms results in a distortion of the molecular cage of the cavitand and in the loss of symmetry for the whole system.…”
Section: Reactivity Of P(iii)-phosphocavitandsmentioning
confidence: 99%
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