We solve the metrisability problem for the six Painlevé equations, and more generally for all 2nd order ODEs with Painlevé property, and determine for which of these equations their integral curves are geodesics of a (pseudo) Riemannian metric on a surface.A problem of characterising metrisable ODEs by differential invariants was posed by Roger Liouville [21], who has reduced it to an overdetermined system of linear PDEs (see Theorem 2.1 in the next section). The complete solution was provided relatively recently [1], where it was shown that an ODE is metrisable if and only if three point invariants of differential orders five and six vanish, and certain genericity assumptions hold.A different approach was developed by Painlevé, Kowalevskaya and Gambier who studied 2nd order ODEs in the complex domain [24,16].Definition 1.2. The ODE y ′′ = R(x, y, y ′ ), where R is a rational function of y and y ′ has the Painlevé property (PP) if its movable singularities (i.e. singularities whose locations depend on the initial conditions) are poles.The solutions of equations with Painlevé property are single-valued thus giving rise to proper functions on C. There exists fifty canonical types of second order ODEs with PP