The 192Hg nucleus was populated in the 16~ 4n) reaction at a beam energy of E= 159 MeV. Emitted 7-rays were detected with the EUROGAM array comprising 43 Compton-suppressed large volume Ge detectors. The level scheme of 192Hg has been extended up to an excitation energy ofE = 10.4 MeV and spin I = 34 h.Two new structures, made of competing AI= 1 and AI = 2 transitions have been observed and their connexions with the low-lying levels established. Their lowest levels are located at 6.304 MeV and 6.879 MeV excitation energy. The experimental results are compared with mean-field HF+ BCS calculations. It is proposed that the new structures originate from deformationaligned quasi-proton excitations n(i13/2*h9/2)K=11 and 7r(h9/2)2=8, coupled to rotation-aligned quasi-neutron v(ils/y and quasi-proton rc (hi 1~2) 2 excitations.