The decarbonization of the energy system requires the adoption of a mix of zero or low carbon intensive technological options, which depends on their cost-effectiveness, their potential to reduce emissions and on social acceptance issues. Transport electrification combined with renewable energy sources (RES) deployment in power generation is a key decarbonization option assessed in many recent studies that focus on national or international climate policies. The penetration of electric vehicles (EVs) together with a gradual retirement of conventional oil-fuelled vehicles implies that a new ‘trade ecosystem’ will be created characterized by different features (move from OPEX to CAPEX) and supply chains. A key component of the EVs are the Lithium-Ion batteries, the manufacturing of which is employment intensive and constitutes an essential element of the EVs that can act as a driver for establishing comparative advantages and increasing EV market shares. Our study focuses on the size of the EV market that can be established within ambitious global and EU decarbonization scenarios and investigates the economic, trade and employment implications considering the production chain of EVs (i.e., the regional production of batteries and vehicles). We use the large-scale global GEM-E3-FIT model to capture the trade dynamics of decarbonization scenarios. We find that under ambitious climate policies, the global size of the clean energy technologies will be US$44 trillion cumulatively over the 2020–2050 period. 44per cent of the market relates to EVs, which will mostly be produced outside EU. For the EU to capture a significant segment of the EV value chain, it needs to increase clean energy R&D and associated supportive policies so as to boost the domestic capacity to produce competitively batteries. JEL: F11, F13, F16, F18, F62, F68