Many modern and proposed future particle accelerators rely on superconducting radio frequency cavities made of bulk niobium as primary particle accelerating structures. Such cavities suffer from the anomalous field dependence of their quality factors Q 0 . High field degradation -so-called 'high field Q-slope' -is yet unexplained even though an empirical cure is known. Here we propose a mechanism based on the presence of proximity-coupled niobium hydrides, which can explain this effect. Furthermore, the same mechanism can be present in any surface-sensitive experiments or superconducting devices involving niobium.PACS numbers: 74.25.nn, 74.45.+c, 81.65.-b, 85.25.-j arXiv:1212.3384v3 [cond-mat.supr-con]