“…[31][32] Lastly, we investigate hysteresis in the desorption process using the first order reversal curve (FORC) technique, 34 which can provide insight into intrinsic properties and interactions in hysteretic systems. [35][36][37][38][39][40] Using a procedure analogous to previous studies, the sample is initially prepared in the un-hydrogenated state, then dosed with hydrogen, driving it to a reversal pressure, PR, at which point the sample is in a mixed state of Pd and PdHx. After reaching PR, the applied pressure, P, is decreased while measuring the net absorption, Q(P, PR), and the sample is This may suggest that both the Pd and the PdH phases could be changing composition, and a combination of thermodynamic and kinetic factors may be at play.…”