First principle calculation of nonlinear optical response of (D/L)-Alanine in chiral carbon nanotube

Recent Advances in Separation and Analysis of Chiral Compounds

“…CNTs have also been functionalized with chiral selectors and used as substrates to achieve chiral separation. 153,164,165 Chiral CNTs were synthesized as a unique type of chiral nanomaterial, 166,167 but they were never applied for chiral membranes because of the difficulty of obtaining pure chiral CNTs.…”

“…The porous graphene with controlled and nanosized pores was immobilized on an ultrafiltration membrane for enantioselective separation of d / l -amino acids, achieving high separation factor of 4.76 for d / l -phenylalanine. CNTs have also been functionalized with chiral selectors and used as substrates to achieve chiral separation. ,, Chiral CNTs were synthesized as a unique type of chiral nanomaterial, , but they were never applied for chiral membranes because of the difficulty of obtaining pure chiral CNTs.…”

Coordination mode and stability of the tetrahydroborate ligand in group 10 metal pincer complexes

“…Atoms in Molecules (AIM) topology analysis and Interaction Region Indicator (IRI) analysis were extensively used to explore bonding in different systems. [21][22][23][24][25][26] In order to further confirm the coordination and that of Pt-PBP displayed absorptions at 2393 and 2082 cm −1 , corresponding to the B-H t and B-H b stretching vibrations. 1,4 The spectral pattern is similar to that of the related pincer nickel and palladium complexes with a η 2 -H 2 BH 2 ligand.…”

“…Atoms in Molecules (AIM) topology analysis and Interaction Region Indicator (IRI) analysis were extensively used to explore bonding in different systems. 21–26 In order to further confirm the coordination mode of the BH 4 − ligand in Pt-POCOP , we performed the AIM and IRI analyses. The results are presented in Fig.…”

Metalloborospherenes with a Stabilized Classical Fullerene-like Borospherene B40 Act as Nonlinear Optical Switches, Electron Reservoirs, Molecular Capacitors, and Molecular Reactors

“…Designing novel materials with superior nonlinear optical (NLO) properties has attracted considerable interest in light of their widespread applications. Some interesting works involving chiral nanotubes have been reported. ,− Nonlinear optical (NLO) switches can be described as molecules converting between two or more forms, displaying contrasts in NLO properties . Owing to the fact that exohedral metalloborospherenes have dispersive and easily polarized excess electrons, they are very suitable as external electric field-manipulated nonlinear optical NLO switches.…”