Flammability limits play an important
role in combustion research,
industrial applications, and fire safety. This article provides a
comprehensive review of recent developments in the fundamental understanding
of flammability limits and their experimental determination as well
as estimation methods for pure fuels and fuel mixtures. The article
begins with a discussion of the importance and challenges of determining
flammability limits. It then presents the theoretical, computational,
and experimental methods available to understand the mechanism of
flammability limits and to quantify them. The experimental setups
using cylindrical and spherical vessels to determine the flammability
limits are discussed. The effects of buoyancy, thermal radiation,
and flame stretch are examined. The relationship between the fundamental
flammability limits and the extinction limits of stretched flames
via strain and radiation is presented. The effects of initial temperature,
pressure, mixtures of different fuels, and diluents are examined,
and available estimation methods are presented. Finally, the flammability
limits of renewable and alternative fuels are addressed and strategies
for estimating the flammability limits of these fuels are presented.