A prompt transport of radiation induced
free carriers toward luminescence
centers is a key factor for an efficient conversion of high energy
radiation into light in scintillator materials. However, the transport
stage of the scintillation process can be hampered by the presence
of lattice imperfections. In this study, we investigated the increase
of radioluminescence (RL) efficiency after prolonged material irradiation.
The general character of the phenomenon was revealed by its occurrence
in several scintillator crystals like Lu2Si2O7:Pr, Bi3Ge4O12, Lu3Al5O12:Ce, and Lu0.3Y0.7AlO3:Ce. A detailed investigation was carried
out for Lu2Si2O7:Pr. We demonstrated
that the RL efficiency increase is due to the progressive filling
of traps responsible for the thermoluminescence glow peaks at 460
and 515 K, which compete with Pr3+ centers in free carrier
trapping during irradiation. Correspondingly, their emptying results
in the recovery of the initial lowest RL efficiency. Spatial correlation
between traps and Pr3+ ions was evidenced by the detection
of an a-thermal tunneling afterglow between trap levels and 4f excited
states of Pr3+. Such hysteresis phenomenon represents a
memory of previous irradiations that remains stored in the crystal.
It is a further effect caused by traps, which deserves attention like
other manifestations of defects in scintillators like the reduction
of light yield and the occurrence of slow tails in the scintillation
time decay.