Superhydrophobic surfaces with outstanding liquid-repellent
properties
have potential applications in anti-icing, self-cleaning, and corrosion
protection, which rely on a stable gas–liquid interface and
low surface energy for passive protection. However, there are still
challenges in overcoming physical damage of the superhydrophobic surface
and integrating self-healing and active deicing properties to boost
their practical application. Here, we report a photothermal MOF-based
superhydrophobic coating with synergistic protective functions of
passive liquid-repellent properties (for self-cleaning, anti-icing,
and anticorrosion) and active photothermal responsiveness (for deicing
and photothermal self-healing). The multifunctional coating was prepared
by the spray-coating method, in which fluoridated photothermal ferrocene-MOF
nanosheets and SiO2 nanoparticles were applied in epoxy
resin to develop their versatility. Passive liquid-repellent properties
of the superhydrophobic surface caused high-efficiency removal of
solid and liquid contaminants, freezing delay of droplets, and corrosion
resistance. Moreover, rapid active deicing performance was achieved
without damaging the textural structure of the coating. Importantly,
the superhydrophobicity of the surface was maintained after mechanical
abrasion. Also, the liquid-repellent properties of the plasma-etched
coating recovered rapidly with light illumination due to the photothermal-induced
migration of fluorosilane chains. Therefore, the synergy of passive
liquid-repellent properties and active photothermal responsiveness
provides a strategy for the design of multifunctional coating.