Biobased composites
with peculiar properties offer an attractive
route for producing environmentally friendly materials. The reinforcement
for poly(butylene adipate-
co
-terephthalate) (PBAT),
based on zein-titanium dioxide (TiO
2
) complex (ZTC) microparticles,
is presented and used to produce composite filaments, successfully
3-dimensionally (3D) printed by fused deposition modeling (FDM). The
outcome of ZTC addition, ranging from 5 to 40 wt %, on the thermo-mechanical
properties of composite materials was analyzed. Results reveal that
storage modulus increased with increasing the ZTC content, leading
to a slight increase in the glass transition temperature. The creep
compliance varies with the ZTC concentration, denoting a better resistance
to deformation under constant stress conditions for composites with
higher complex content. Scanning electron microscopy was used to assess
the quality of interphase adhesion between PBAT and ZTC, showing good
dispersion and distribution of complex microparticles in the polymer
matrix. Infrared spectroscopy confirmed the formation of a valid interface
due to the formation of hydrogen bonds between filler and polymer
matrix. Preliminary tests on the biocompatibility of these materials
were also performed, showing no cytotoxic effects on cell viability.
Finally, the 3D printability of biobased composites was demonstrated
by realizing complex structures with a commercial FDM printer.