Flocculation of alkyl ketene dimer and calcium carbonate on paper sizing and filling performance

Abstract

In order to solve the conflict between precipitated calcium carbonate (PCC) filling and alkyl ketene dimer (AKD) sizing for paper, this study explored two new flocculation methods: AKD and PCC were flocculated separately in the process ((A)(P)F), while the two pre-flocs from AKD and PCC were blended in the process ((AP)F). The result showed that increasing the dosage of the flocculant cationic starch (CS) resulted in a significant growth in the median size of PCC flocs and reduction in the specific surface area, turbidity, the negative charge of Zeta potential, as well as the adsorption capacity of PCC to AKD. Consequently the sizing degree and filler retention rate of the handsheets rose markedly. With 125 mg g−1 of CS, compared with the conventional process, the filler retention rate for (A)(P)F grew up to 86.16%; the Cobb60 values for both (AP)F and (A)(P)F declined, and the contact angle (CA) increased to 120.65° and 127.65° respectively. At the same time, the filler bondability factor (FBF) were increased due to the intensified bonding force between fibers, and resultantly the comparable mechanical properties of papersheets with a high level of filler retention was obtained from (AP)F and (A)(P)F flocculation processes.