By integration of a PyENG, a PVC, and a triboelectric-piezoelectric nanogenerator (TPiENG) into one device and the same output electrodes, the multi-effects coupled nanogenerator is able to individually/simultaneously scavenge the thermal, solar, and mechanical energies. As compared with the individual TPiENG, both the individual PyENG and individual PVC have the much higher output voltage but much smaller output current. The multi-effects coupled nanogenerator combines the advantages of all the individual units, which can generate electricity with a large peak current of ≈5 µA, a high peak voltage of ≈80 V, and a high platform voltage of ≈50 V. The multi-effects coupled nanogenerator of "PyENG + PVC + TPiENG" exhibits the best charging performance and a 10 µF capacitor can be easily charged to 5.1 V in 90 s, which is prospective for maximizing energy scavenging from the surrounding environments. Solar, mechanical, and thermal energies are commonly available in our surrounding environment, either existing alone or coexist. Combining the integration of various energy harvesters and the couple of multiple energy sources, that is, the coupled technology toward multi-energy scavenging (Figure 1a), represents a newly rising field in energy research. Based on piezo-tribo-pyro-photoelectric effects, we design a one-structure-based multi-effects coupled nanogenerator, as illustrated in Figure 1b. The nanogenerator is mainly composed of three parts: PZT block, which is the piezoelectric, pyroelectric, and photoelectric active material; polyamide (nylon), which not only acts as the flexible vibrating film to introduce triboelectrification with fluorinated ethylene propylene (FEP) film but also applies strain to neighboring PZT during vibration; a thin silver (Ag) film under the PZT for the bottom electrode and a thin indium tin oxide (ITO) film combined with Ag nanowires/ polydimethylsiloxane (AgNWs/PDMS) film were introduced for the top electrode. In final, a thermoelectric (TE) module supported by a radiator provides the temperature adjunction of the device. Detailed fabrication process of the nanogenerator is given in the Experimental Section. Figure 1c presents a photo of the fabricated one-structure-based coupled nanogenerator. Anyhow, the multi-effects coupled nanogenerator integrates the PyENG, the PVC, and the TPiENG into one device and the same output electrodes. Thus, it can be used to simultaneously or individually scavenge the thermal, solar, and mechanical energies whenever and wherever one or all of the energy resources are available. From scanning electron microscopy (SEM) image of the AgNWs (Figure 1d), it can be seen that the lengths of as-prepared AgNWs are in the range of 5-15 µm, accompanied by an aspect ratio of ≈100. The dense and staggered AgNWs network ensures the conductivity of top electrode, while the cross-linked PDMS film makes the AgNWs network mechanically robust. [24] With growing interest in self-powered micro/nanosystems, energy harvesters based on various mechanisms have been widely studi...