Introduction:
Crude oil is a complex blend of various hydrocarbon families, with compositions
that vary depending on the source well and exploitation duration. To categorize its constituents,
SARA analysis divides them into saturated, aromatic, resins, and asphaltenes. Heavy asphaltene-
rich crude oils can present challenges like viscosity and pipeline blockages, which are often
addressed with viscosity-reducing additives. However, a theoretical framework explaining how these
additives affect crude oil is lacking, relying primarily on empirical observations. To optimize these
additives, it is crucial to understand the underlying chemical and physical processes. This study hypothesizes
that asphaltenic crude oils influence viscosity through colloidal properties linked to molecular
interactions.
Methods:
The research aimed to analyze the impact of sulfur in asphaltenes and oxygen in flow improvers
on the transport properties of an idealized crude oil, with the goal of predicting additive feasibility.
A methodology that combined computational quantum chemistry and statistical thermodynamics
was used. An idealized model of crude oil was created, consisting of non-polar alkanes and
polar asphaltenes with sulfur atoms. A flow improver was simulated with an aromatic-aliphatic structure
containing oxygen and hydroxyl groups, and viscosity was calculated.
Results:
This study assessed the transport properties of the mixture using principles of statistical
thermodynamics. The theoretical insights revealed that reducing viscosity in asphaltene-rich crude
oils with additives depends on several critical factors, including the formation of the dispersed phase,
the reduced viscosity of the additive, and the effects of dilution. The research identified a strong link
between the enhanced effectiveness of these additives and their structural and molecular properties.
Conclusion:
The theoretical results suggest that additives that act as viscosity reducers in asphalt
crudes achieve optimal performance when they possess both higher polarity and reduced viscosity.