Flow-injection chemiluminescent determination of nitrite in water based on the formation of peroxynitrite from the reaction of nitrite and hydrogen peroxide

Lu, Chao; Feng, Qi; Lin, Jin‐Ming; Yamada, Masaaki

doi:10.1016/s0003-2670(02)01010-3

Cited by 63 publications

(54 citation statements)

References 31 publications

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“…In this present work, the CL signal was produced by the decomposition of ONOO − into NO − and singlet oxygen (the proposed CL emitter), which had been discussed in our previous work [14]. ONOO − was generated from ONOOH in basic solution, and ONOOH was produced as a result of the reaction between nitrite and hydrogen peroxide in the presence of an acidic catalyst.…”

Section: Methodsmentioning

confidence: 63%

“…Based on our previous work [14], a concentration of 0.1 mol l −1 HCl was chosen in further experiments.…”

Section: Optimal Conditions For the Fia-cl Systemmentioning

confidence: 99%

“…ONOO − was generated from peroxynitrous acid (ONOOH) in NaOH solution, and ONOOH was produced as a result of the reaction of nitrite with acidified hydrogen peroxide [13]. In our previous work [14], a flow injection CL method for the determination of nitrite was reported due to the decomposition of ONOO − into NO − and singlet oxygen ( 1 O 2 ) (the proposed CL emitter) in the presence of a suitable surfactant (at concentration above its CMC) and a sensitizer (uranine). In the present work, bilirubin and its conjugate were also found to enhance remarkably the CL emission generated from the nitrite-hydrogen peroxide reaction in a suitable micellar solution and was utilized for the determination of total bilirubin contents in human serum.…”

Section: Introductionmentioning

confidence: 99%

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Determination of total bilirubin in human serum by chemiluminescence from the reaction of bilirubin and peroxynitrite

Lin

Huie

2004

Talanta

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Peroxynitrous acid (ONOOH) was produced by the on-line reaction of acidified hydrogen peroxide with nitrite in a flow system, and peroxynitrite (ONOO − ) was generated from ONOOH in NaOH solution. A weak chemiluminescent (CL) emission was observed due to the production of singlet oxygen ( 1 O 2 ) during the decomposition of ONOO − . Bilirubin and its conjugate were found to enhance the CL emission of 1 O 2 in a suitable micellar medium. For the first time, the feasibility of employing the present CL system for the sensitive and selective determination of total bilirubin contents in human serum was demonstrated and the results were compared with certified values. The present method showed a great improvement on overcoming bis(2,4,6-trichlorophenyl)oxalate CL highly insolubility in aqueous solution and exhibiting higher tolerance towards interferences than redox reaction of bilirubin with various oxidizing agents such as sodium hypochlorite and iodine. The recoveries of bilirubin were found to fall in the range between 95 and 108%. The detection limits (S/N = 3) for bilirubin and its conjugate were determined to be 10 and 8 ng ml −1 , respectively. The relative standard deviations (R.S.D.) for the consecutive CL detection of a series of bilirubin (30 g l −1 ) and bilirubin ditaurite (25 g l −1 ) were 3.2 and 2.9% (n = 11), respectively.

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Section: Methodsmentioning

confidence: 63%

“…Based on our previous work [14], a concentration of 0.1 mol l −1 HCl was chosen in further experiments.…”

Section: Optimal Conditions For the Fia-cl Systemmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Determination of total bilirubin in human serum by chemiluminescence from the reaction of bilirubin and peroxynitrite

Lin

Huie

2004

Talanta

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“…18 fluorometric 19 and CL 20,21 methods. In the present study, we found that the CL intensity is proportional to the concentration of nitrite in the range from 0.1 to 100 mM.…”

Section: Electrochemicalmentioning

confidence: 99%

Determination of nitrite in tap waters based on fluorosurfactant-capped gold nanoparticles-enhanced chemiluminescence from carbonate and peroxynitrous acid

et al. 2011

Analyst

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Fluorosurfactant (FSN)-capped gold nanoparticles (GNPs), which exhibit higher stability at a wider pH range and high ionic strength, were utilized for investigating the chemiluminescence (CL) effect on the reaction between high concentration carbonate ($0.3 M) and peroxynitrous acid. When the pH of the colloidal solution was 10.2 by dropwise addition of 0.05 M NaOH, FSN-capped GNPs offer an enhanced CL intensity. Based on the CL spectra, XPS spectra and the quenching effect of reactive oxygen species, a possible CL mechanism is proposed. The tolerance of FSN-capped GNPs towards salt concentrations (salt proofing effect) within a large pH range is an interesting feature, compared to the other previously reported work on nanoparticles CL systems. The CL intensity is proportional to the concentration of nitrite in the range from 0.1 to 100 mM. The detection limit (S/N ¼ 3) is 0.036 mM and the relative standard deviation (RSD) for seven repeated measurements of 0.5 mM nitrite was 2.4%. This method has been successfully applied to determine nitrite in tap waters with recoveries of 97-106%.

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“…However, these absorption methods are time consuming and highly insensitive. In recent years, chemiluminescence (CL) has shown good potential as an attractive technique for routine usage in clinical laboratories due to its outstanding advantages in terms of limits of detection, selectivity, instrumental simplicity, speed of analysis, and linear dynamic range [16]. Huie and co-workers [17] were the first to demonstrate the feasibility of detecting CL emission from bilirubin in organic solvents, based on the transfer of energy from the reaction intermediate(s) of the peroxyoxalate CL reaction.…”

Section: Introductionmentioning

confidence: 99%

Enhancement in sample preconcentration by the on-line incorporation of cloud point extraction to flow injection analysis inside the chemiluminescence cell and the determination of total serum bilirubin

Song

Lin

et al. 2007

Analytica Chimica Acta

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Flow-injection chemiluminescent determination of nitrite in water based on the formation of peroxynitrite from the reaction of nitrite and hydrogen peroxide

Cited by 63 publications

References 31 publications

Determination of total bilirubin in human serum by chemiluminescence from the reaction of bilirubin and peroxynitrite

Determination of total bilirubin in human serum by chemiluminescence from the reaction of bilirubin and peroxynitrite

Determination of nitrite in tap waters based on fluorosurfactant-capped gold nanoparticles-enhanced chemiluminescence from carbonate and peroxynitrous acid

Enhancement in sample preconcentration by the on-line incorporation of cloud point extraction to flow injection analysis inside the chemiluminescence cell and the determination of total serum bilirubin

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