Wet granular materials are characterized by a defined bond energy in their particle interaction such that breaking a bond implies an irreversible loss of a fixed amount of energy. Associated with the bond energy is a nonequilibrium transition, setting in as the granular temperature falls below the bond energy. The subsequent aggregation of particles into clusters is shown to be a self-similar growth process with a cluster size distribution that obeys scaling. In the early phase of aggregation the clusters are fractals with D f = 2, for later times we observe gelation. We use simple scaling arguments to derive the temperature decay in the early and late stages of cooling and verify our results with event-driven simulations.PACS numbers: 61.43.Hv Granular systems have encountered strongly increasing interest within recent years [1, 2] as they are both close to industrial applications and relevant as model systems for collective systems far from thermal equilibrium. Most research has focused on dry granulates resulting in rich non-equilibrium phenomena [3]. The dramatic change of mechanical properties due to some wetting liquid additive is apparent, when we compare the fluid-like state of dry sand flowing through an hourglass with the shapeable plastic state of wet sand, which is suitable for molding a sandcastle. This change in bulk properties can be attributed to the differences in the underlying particle interactions [4,5]. Whereas in collisions of dry particles, a certain fraction of the initial kinetic energy is dissipated into the atomic degrees of freedom of the particles, in the wet case, the interaction is mainly due to the interfacial forces exerted by liquid capillary bridges which form between adjacent particles and dissipate energy upon rupture.More recently, the dynamics of wet granular media has been addressed in several studies [5,6,7,8,9, 10], focusing on nonequilibrium phase transitions [10], agglomeration [6,7], shear flow [8] and cooling in one dimension [9]. A particularly important aspect of free cooling in cohesive gases is the structure of the emerging clusters. It pertains to the formation of dust filaments and the microscopic mechanisms of cloud formation as well as to the size distribution and impact probability of planetesimals in accretion discs. Structure formation in wet granulates during free cooling has hardly been studied yet and is the central theme of our paper. We suggest a very simple model for the interaction of two wet grains, which only takes into account the essential features of a capillary bridge: hysteresis and dissipation with a well defined energy loss. Cooling is controlled by the proba- * Electronic address: ulrich@theorie.physik.uni-goettingen.de bility for a bridge to rupture and hence logarithmically slow in the long time limit, when a percolating structure has been formed. For smaller times the structure is characterized by coexisting fractal clusters of all sizes, whose size distribution is shown to scale.Model-Consider a gas of N hard spheres of diameter d ...