The coupled momenta induced by thermal effects near interfaces cause complex three-dimensional flow structures, called thermocapillary flow or Marangoni convection. Thermocapillary convection is crucial for crystal growth quality, and the mainstream method used to study thermocapillary convection is the half-zone liquid bridge model. This paper designs a gas–liquid two-phase system and reports the numerical results on the instability and associated roll structures of thermocapillary convection in half-zone liquid bridge under microgravity environment. The gas and liquid transferred momentum and energy through the free surface. The geometry of interest is high aspect ratio (AR) silicone oil suspended between coaxial disks heated differentially. It was found that with the increase in AR, the vortex of thermocapillary convection gradually moves to the upper disk at the steady state. In the range of 2 < AR < 2.5, the vortex cell splits from 1 to 2, and the distance between the vortex center increases with the increase in AR. The flow field after the onset of instability exhibits a traveling wave with wave number m = 1 when AR ≤ 3 and exhibits a standing wave with wave number m = 1 when AR ≥ 3.5.