The anodizing behavior of a dissimilar friction stir weld of AA5083-O and AA6082-T6 alloys in 4 M H 2 SO 4 solution has been investigated. The anodizing results show that the AA5083-O rich zones were more oxidized during anodizing compared with the AA6082-T6 rich zones. Interestingly, the nugget and the thermomechanically affected regions of the individual parent alloys showed significant reduction in porous anodic oxide thicknesses. Sputtering-deposition of pure aluminum on the weld, prior to anodizing, significantly minimized the variations in the oxide thicknesses across the weld. More importantly, this method prevented the boundary dissolution (associated with the activity of the Mg 2 Si phase) that is often observed after anodizing the dissimilar weld of the alloys. © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0651512jes] All rights reserved. Friction stir welding is a solid state joining process that employs the frictional heat generated as a result of the motion between a nonconsumable rotating tool and the work pieces to produce welds. In the last two decades, since its invention in 1991, friction stir welding has become a highly reliable joining technique based on its principal advantage of being able to produce welds in the solid state with low heat spread. [1][2][3] In the transport industry, lightweighting is highly desired as well as multi-functionality of components which can be readily achieved by using multi-material components. Friction stir welding can produce multi-material component welds with minimal defects compared with fusion welding techniques. However, a common feature of all welding process is that zonal heterogeneities are often generated with consequent galvanic cells in the welds, which will be particularly pronounced in welds of dissimilar materials. 4 These galvanic cells can lead to undesirable corrosion failures in service. In a bid to reduce corrosion susceptibilities in friction stir welds, post weld heattreatment/artificial aging, 3,5-7 laser surface melting, [8][9][10][11][12] cold sprayed aluminum 13 and micro-arc oxidation coating 14 have been employed in recent times. Whilst post weld heat-treatment has been reported to improve the corrosion resistance of certain friction stir welded aluminum alloys 3,7 and to improve the mechanical properties of the low-strength weld regions ,15 its suitability for in-service applications is in doubt because of the timing involved and the large structure sizes employed commercially.7 Laser surface melting has been reported to improve the corrosion resistance of friction stir welded aluminum alloys throu...