2012
DOI: 10.1016/j.materresbull.2012.08.009
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Flower-like and hollow sphere-like WO3 porous nanostructures: Selective synthesis and their photocatalysis property

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Cited by 89 publications
(38 citation statements)
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“…Tungsten oxide (including tungsten oxide hydrate), as a kind of n-type semiconductor material, has been intensively studied due to their good optical and electrical properties, and the potential applications in lithium batteries, electrochromic windows, gas sensors and photocatalysis [17][18][19][20][21]. Furthermore, the tungsten oxide-based materials appear some different crystal structures including tungsten bronze-type hexagonal, pyrochlore-type cubic and so on, which suggests a potential in constructing homojunction photocatalysts.…”
Section: Introductionmentioning
confidence: 99%
“…Tungsten oxide (including tungsten oxide hydrate), as a kind of n-type semiconductor material, has been intensively studied due to their good optical and electrical properties, and the potential applications in lithium batteries, electrochromic windows, gas sensors and photocatalysis [17][18][19][20][21]. Furthermore, the tungsten oxide-based materials appear some different crystal structures including tungsten bronze-type hexagonal, pyrochlore-type cubic and so on, which suggests a potential in constructing homojunction photocatalysts.…”
Section: Introductionmentioning
confidence: 99%
“…The C=S bond destroys the hydrogen bonds between the layers in the rim, making the lamellar structure unstable, which later scrolls to form microtubes. The flower-like morphology takes place either by self organization (oriented attachment) [39] or by the dissolution of small nanoflakes (Ostwald ripening) [80]. The formation of hollow spheres proceed only through Ostwald ripening process, wherein dissolution of core occurs as a result of high surface energy and precipitates as larger particles, which segregates at the shell [80].…”
mentioning
confidence: 99%
“…When CA is not added during synthesis process, as we can see from The above observations indicate that the presence of CA strongly influences the morphologies of WO 3 products. The formation of WO 3 flower-like hierarchical architectures maybe attributed to the Ostwald ripening process and self assembly process [20,28,29]. Sodium tungstate (Na 2 WO 4 ·2H 2 O) was used as tungsten source, which was first dissolved in deionized water forming colorless solution.…”
Section: Structure Characterizationsmentioning
confidence: 99%