Flower-like NiCo2O4 nanoflake surface covered on carbon nanolayer for high-performance electro-oxidation of non-enzymatic glucose biosensor

Sivakumar, Mani; Vivekanandan, A.K.; Panomsuwan, Gasidit; Veeramani, V.; Chen, S.-H.; Jiang, Zhongqing; Maiyalagan, T.

doi:10.1016/j.mtchem.2022.101156

Cited by 6 publications

(8 citation statements)

References 39 publications

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“…Shape and structure also affect material properties. Sivakumar et al [ 75 ] synthesized Co 2 O 4 -NF with flower-like structure by a simple hydrothermal method for nonenzymatic glucose sensing ( Figure 10 ). A floral structure of C/NiCo 2 O 4 -1 NF material covers a carbon surface.…”

Section: Biomimetic Nanomaterialsmentioning

confidence: 99%

“… SEM images of ( A , B ) NiCo 2 O 4 follower, ( C , D ) C/NiCo 2 O 4 -1 follower, and ( E , F ) C/NiCo 2 O 4 -2 flake; ( G – K ) the elemental mapping of C/NiCo 2 O 4 -1; ( L ) the amperometry profile of C/NiCo 2 O 4 -1 NF@GCE with a low to high concentration of glucose from 0.0001 to 15.28 mM [ 75 ] with permission (Copyright © 2022, Elsevier). …”

Section: Figurementioning

confidence: 99%

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Research Progress on Biomimetic Nanomaterials for Electrochemical Glucose Sensors

Chi

Zhang

et al. 2023

Biomimetics

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Diabetes has become a chronic disease that necessitates timely and accurate detection. Among various detection methods, electrochemical glucose sensors have attracted much attention because of low cost, real-time detection, and simple and easy operation. Nonenzymatic biomimetic nanomaterials are the vital part in electrochemical glucose sensors. This review article summarizes the methods to enhance the glucose sensing performance of noble metal, transition metal oxides, and carbon-based materials and introduces biomimetic nanomaterials used in noninvasive glucose detection in sweat, tear, urine, and saliva. Based on these, this review provides the foundation for noninvasive determination of trace glucose for diabetic patients in the future.

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Section: Biomimetic Nanomaterialsmentioning

confidence: 99%

Section: Figurementioning

confidence: 99%

Research Progress on Biomimetic Nanomaterials for Electrochemical Glucose Sensors

Chi

Zhang

et al. 2023

Biomimetics

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“…Recently, various carbonbased materials have been utilized to enhance the properties of metal oxides. The most used are reduced graphene oxide (rGO), [29][30][31] graphene, [32][33][34] activated carbon, [35][36][37] g-C 3 N 4 , 38,39 and carbon nanotubes (CNT). 40 They have excellent properties, such as large surface area and good conductivity, but their fabrication process from commercial precursors is however costly and environmentally harmful.…”

Section: Introductionmentioning

confidence: 99%

High electrochemical performance of nickel cobaltite@biomass carbon composite (NiCoO@BC) derived from the bark of Anacardium occidentale for supercapacitor application

Diop,

Ndiaye,

Dieng

et al. 2024

RSC Adv.

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“…For example, Ni has a very strong affinity toward histidine. 13 This interaction typically involves the nitrogen atom of the imidazole ring of histidine coordinating with the Ni 2+ ion. 16 Such interactions are often used in molecular biology setups for the affinity-based purification of histidine-tagged genetically modified protein molecules.…”

Section: ■ Introductionmentioning

confidence: 99%

“…Moreover, the conjugation chemistry associated with pseudocapacitive nanomaterials has not been extensively explored for biosensing applications. For example, Ni has a very strong affinity toward histidine . This interaction typically involves the nitrogen atom of the imidazole ring of histidine coordinating with the Ni 2+ ion .…”

Section: Introductionmentioning

confidence: 99%

A Redox Mediator-Free Highly Selective and Sensitive Electrochemical Aptasensor for Patulin Mycotoxin Detection in Apple Juice Using Ni–NiO Pseudocapacitive Nanomaterials

Datta,

Bhatt,

Dutta

2024

J. Agric. Food Chem.

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Pseudocapacitive nanomaterials have recently gained significant attention in electrochemical biosensors due to their rapid response, long cycle life, high surface area, biomolecule compatibility, and superior energy storage capabilities. In our study, we introduce the potential of using Ni−NiO nanofilm's pseudocapacitive traits as transducer signals in electrochemical aptasensors. Capitalizing on the innate affinity between histidine and nickel, we immobilized histidine-tagged streptavidin (HTS) onto Ni−NiOmodified electrodes. Additionally, we employed a biolayer interferometry-based SELEX to generate biotinylated patulin aptamers. These aptamers, when placed on Ni−NiO−HTS surfaces, make a suitable biosensing platform for rapid patulin mycotoxin detection in apple juice using electrochemical amperometry in microseconds. The novelty lies in optimizing pseudocapacitive nanomaterials structurally and electrochemically, offering the potential for redox mediator-free electrochemical aptasensors. Proof-of-concept is conducted by applying this surface for the ultrasensitive detection of a model analyte, patulin mycotoxin. The aptamer-functionalized bioelectrode showed an excellent linear response (10−10 6 fg/mL) and an impressive detection limit (1.65 fg/mL, +3σ of blank signal). Furthermore, reproducibility tests yielded a low relative standard deviation of 0.51%, indicating the good performance of the developed biosensor. Real sample analysis in freshly prepared apple juice revealed no significant difference (P < 0.05) in current intensity between spiked and real samples. The sensor interface maintained excellent stability for up to 2 weeks (signal retention 96.45%). The excellent selectivity, stability, and sensitivity of the electrochemical aptasensor exemplify the potential for using nickelbased pseudocapacitive nanomaterials for a wide variety of electrochemical sensing applications.

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Flower-like NiCo2O4 nanoflake surface covered on carbon nanolayer for high-performance electro-oxidation of non-enzymatic glucose biosensor

Cited by 6 publications

References 39 publications

Research Progress on Biomimetic Nanomaterials for Electrochemical Glucose Sensors

Research Progress on Biomimetic Nanomaterials for Electrochemical Glucose Sensors

High electrochemical performance of nickel cobaltite@biomass carbon composite (NiCoO@BC) derived from the bark of Anacardium occidentale for supercapacitor application

A Redox Mediator-Free Highly Selective and Sensitive Electrochemical Aptasensor for Patulin Mycotoxin Detection in Apple Juice Using Ni–NiO Pseudocapacitive Nanomaterials

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