We examine fundamental properties of Green's functions of Nambu-Goldstone and Higgs modes in superconductors with multiple order parameters. Nambu-Goldstone and Higgs modes are determined once the symmetry of the system and that of the order parameters are specified. Multiple Nambu-Goldstone modes and Higgs modes exist when we have multiple order parameters. The Nambu-Goldstone Green function D(ω, q) has the form 1/(gN (0)) 2 · (2∆) 2 /(ω 2 − c 2 s q 2 ) with the coupling constant g and cs = vF / √ 3 for small ω and q, with a pole at ω = 0 and q = 0 indicating the existence of a massless mode. It is shown, based on the Ward-Takahashi identity, that the massless mode remains massless in the presence of intraband scattering due to nonmagnetic and magnetic impurities. The pole of D(ω, q), however, disappears as ω increases as large as 2∆: ω ∼ 2∆. The Green function H(ω, q) of the Higgs mode is given by H(ω, q) ∝ (2∆) 2 /((2∆) 2 − 1 3 ω 2 + 1 3 c 2 s q 2 ) for small ω and q. H(ω, q) is proportional to 1/(gN (0)) 2 · ∆/ (2∆) 2 + c 2 s q 2 − ω 2 for ω ∼ 2∆ and ω < ω(q) where ω(q) = (2∆) 2 + c 2 s q 2 . This behavior is similar to that of the σ-particle Green function in the Gross-Neveu model. That is, the Higgs Green function H(ω, q) has the same singularity as the Green function of the σ boson of the Gross-Neveu model. The constant part of the action for the Higgs modes is important since it determines the coherence length of a superconductor. There is the case that it has a large eigenvalue, indicating that the large upper critical field Hc2 may be realized in a superconductor with multiple order parameters.