The microstructure
of snow determines its fundamental properties
such as mechanical strength, reflectivity, or thermo-hydraulic properties.
Snow undergoes continuous microstructural changes due to local gradients
in temperature, humidity, or curvature, in a process known as snow
metamorphism. In this work, we focus on wet snow metamorphism, which
occurs when the temperature is close to the melting point and involves
phase transitions among liquid water, water vapor, and solid ice.
We propose a pore-scale phase-field model that simultaneously captures
the three relevant phase change phenomena: sublimation (deposition),
evaporation (condensation), and melting (solidification). The phase-field
formulation allows one to track the temperature evolution among the
three phases and the water vapor concentration in the air. Our three-phase
model recovers the corresponding two-phase transition model when one
phase is not present in the system. 2D simulations of the model unveil
the impact of humidity and temperature on the dynamics of wet snow
metamorphism at the pore scale. We also explore the role of liquid
melt content in controlling the dynamics of snow metamorphism in contrast
to the dry regime before percolation onsets. The model can be readily
extended to incorporate two-phase flow and may be the basis for investigating
other problems involving water phase transitions in a vapor–solid–liquid
system, such as airplane icing or thermal spray coating.