Fluid evolution at the Variscan front in the vicinity of the Aachen thrust

Abstract

Quartz-carbonate-chlorite veins were studied in borehole samples of the RWTH-1 well in Aachen. Veins formed in Devonian rocks in the footwall of the Aachen thrust during Variscan deformation and associated fluid flow. Primary fluid inclusions indicate subsolvus unmixing of a homogenous H 2 O-CO 2 -CH 4 -(N 2 )-Na-(K)-Cl fluid into a H 2 O-Na-(K)-Cl solution and a vapour-rich CO 2 -(H 2 O, CH 4 , N 2 ) fluid. The aqueous end-member composition resembles that of metamorphic fluids of the Variscan front zone with salinities ranging from 4 to 7% NaCl equiv. and maximum homogenisation temperatures of close to 400°C. Pressure estimates indicate a burial depth between 4,500 and 8,000 m at geothermal gradients between 50 and 75°C/26 MPa, but pressure decrease to sublithostatic conditions is also indicated, probably as a consequence of fracture opening during episodic seismic activity. A second fluid system, mainly preserved in pseudo-secondary and secondary fluid inclusions, is characterised by fluid temperatures between 200 and 250°C and salinities of \5% NaCl equiv. Bulk stable isotope analyses of fluids released from vein quartz, calcite, and dolomite by decrepitation yielded dD H2O values from -89 to -113 %, d 13 C CH4 from -26.9 to -28.9% (VPDB) and d 13 C CO2 from -12.8 to -23.3% (VPDB). The low dD and d 13 C range of the fluids is considered to be due to interaction with cracked hydrocarbons. The second fluid influx caused partial isotope exchange and disequilibrium. It is envisaged that an initial short lived flux of hot metamorphic fluids expelled from the epizonal metamorphic domains of the Stavelot-Venn massif. The metamorphic fluid was focused along major thrust faults of the Variscan front zone such as the Aachen thrust. A second fluid influx was introduced from formation waters in the footwall of the Aachen thrust as a consequence of progressive deformation. Mixing of the cooler and lower salinity formation water with the hot metamorphic fluid during episodic fluid trapping resulted in an evolving range of physicochemical fluid inclusion characteristics.

Vývoj metamorfních fluid pozdního stádia regionální metamorfózy v keprnické klenbě silezika

“…Diamond 1994) generované metamorfními podmínkami, které můžeme najít jak v řadě variských, tak i alpských terénů (např. Kaindl et al 1999;Schroyen a Muchez 2000;Sindern et al 2012). V inkluzích III.…”