Fluorinated- and non-fluorinated-diarylamine-Zn(ii) and Cu(ii) phthalocyanines as symmetrical vs. asymmetrical hole selective materials

Abstract

Four symmetrically substituted and four asymmetrically substituted fluorinated and non-fluorinated-diarylamine CuPcs and ZnPcs have been designed and utilized as hole transporting materials in perovskite solar in a planar n-i-p structure....

Graphene Oxide/Cholesterol-Substituted Zinc Phthalocyanine Composites with Enhanced Photodynamic Therapy Properties

“…This peak was not detected in the FT-IR spectrum of Chol-ZnPc, further indicating the successful tetramerization reaction. Also, the IR peaks at about 1522 cm −1 , 1491 cm −1 , 1444 cm −1 , 1398 cm −1 , 1315 cm −1 , 1261 cm −1 , 1144 cm −1 , 1101 cm −1 , 930 cm −1 , 768 cm −1 , and 700 cm −1 could be ascribed to the characteristic skeletal vibrations of ZnPc macrocycles, and were observed in Chol-ZnPc as expected [55][56][57][58][59][60][61][62]. Particularly, the characteristic Pc macrocycle bands at about 1491 cm −1 , 1101 cm −1 , and 768 cm −1 were red-shifted in the GO/Chol-ZnPc, indicating interactions between GO and Chol-ZnPc.…”

Optimization of fluorinated interfacial layers with minimal surface coverage for hybrid perovskite materials

“…16 To this end, the use of bulky alkyl chains, 17 aromatic compounds, 18 or fluorinated derivatives was found to enhance device stability. 6,19 There is thus a significant body of experimental evidence linking surface hydrophobicity and moisture resistance in PSCs. 20…”