Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning

Zhao, Fu‐Gang; Zhao, Gang; Liu, Xinhua; Ge, Congwu; Wang, Jin-Tu; Li, Bai-Li; Wang, Qigang; Li, Weishi; Chen, Qing‐Yun

doi:10.1039/c4ta00847b

Cited by 146 publications

(103 citation statements)

References 28 publications

Supporting

Mentioning

103

Contrasting

Order By: Relevance

“…[26] Due to the covalent character of carbon-fluorine bonds, the chemical and physical properties of fluorinated graphene can be tailored simply by varying the degree of fluorination. [19,[27][28][29] The applicationso f fluorinated graphene includes ensors, [30] transistors, [31] nano electronic devices [32] and spintronics. [33] Several fluorination procedures have been investigated experimentally through exposure of graphenet ov arious fluorinatingagents, includingX eF 2 , [34] F 2 gas, [35] CHF 3 , [36] CF 4 [37] or SF 6 plasma.…”

Section: Introductionmentioning

confidence: 99%

Tuning the Reactivity of Graphene by Surface Phase Orientation

Plšek

Kovaříček

Valeš

et al. 2017

Chemistry A European J

View full text Add to dashboard Cite

Tuning the local reactivity of graphene is a subject of paramount importance. Among the available strategies, the activation/passivation of graphene by copper substrate is very promising because it enables the properties of graphene to be influenced without any transfer procedure, since graphene can be grown directly on copper. Herein, it is demonstrated that the reactivity of graphene towards fluorination is strongly influenced by the face of the surface of the copper substrate. Graphene on the copper foil was probed and grain orientations were identified. The results of the reactivity were evaluated by means of X-ray photo electron and Raman spectroscopy. Graphene on the grains with a surface orientation close to the (111) face is the most reactive, whereas graphene on the grains close to the (110) surface is least reactive. The long-term stability test showed that the decomposition of fluorinated graphene was slowest on the grains with a surface orientation close to the (111) face. The results are consistent with the variation of the mechanical strain of graphene on different faces of copper. In contrast, no clear correlation of the graphene reactivity with doping induced by different facets was found.

show abstract

Section: Introductionmentioning

confidence: 99%

Tuning the Reactivity of Graphene by Surface Phase Orientation

Plšek

Kovaříček

Valeš

et al. 2017

Chemistry A European J

View full text Add to dashboard Cite

show abstract

“…High F‐content (≈10%) of the LIG surface was confirmed by XPS as shown in Figure c–f. Both CF 2 (689 eV) and CF (687 eV) bonds are detected in the F 1s spectrum and the tailing part for C 1s spectrum . Interestingly, elemental S was also identified by the peak position of the S 2p peak (164.5 eV).…”

mentioning

confidence: 96%

Laser‐Induced Graphene in Controlled Atmospheres: From Superhydrophilic to Superhydrophobic Surfaces

et al. 2017

View full text Add to dashboard Cite

The modification of graphene-based materials is an important topic in the field of materials research. This study aims to expand the range of properties for laser-induced graphene (LIG), specifically to tune the hydrophobicity and hydrophilicity of the LIG surfaces. While LIG is normally prepared in the air, here, using selected gas atmospheres, a large change in the water contact angle on the as-prepared LIG surfaces has been observed, from 0° (superhydrophilic) when using O or air, to >150° (superhydrophobic) when using Ar or H . Characterization of the newly derived surfaces shows that the different wetting properties are due to the surface morphology and chemical composition of the LIG. Applications of the superhydrophobic LIG are shown in oil/water separation as well as anti-icing surfaces, while the versatility of the controlled atmosphere chamber fabrication method is demonstrated through the improved microsupercapacitor performance generated from LIG films prepared in an O atmosphere.

show abstract

“…Fluorinated graphene (FG), because of its two‐dimensional (2D) structure and outstanding properties including strong hydrophobicity, low surface energy, corrosion resistance, and thermostability, could be applied to thermoelectric and optoelectronic devices, corrosion resistant coatings, and nanoelectronics . In addition, FG is regarded as a potential filler with lubrication .…”

Section: Introductionmentioning

confidence: 99%

High mechanical and tribological performance of polyimide nanocomposite reinforced by fluorinated graphene oxide

Min

Liang

et al. 2019

Polymer Composites

View full text Add to dashboard Cite

Novel polyimide/fluorinated graphene oxide (PI/FGO) nanocomposites with outstanding mechanical, thermal, and tribological properties were obtained using FGO nanosheets which were successfully fabricated by simple hydrothermal reaction. FGO exhibited distinguished interface adhesion with PI matrix due to covalent bonds, resulting improved mechanical and wear resistance of PI/FGO nanocomposites. Wherein, PI/FGO‐0.5 nanocomposite demonstrated conspicuous tribological performance accompanied with 33.1% decrease of friction coefficient and 80.8% reduction of wear rate compared with pure PI under dry friction. Notably, PI/FGO nanocomposites manifested better wear resistance under seawater than that under dry friction, illustrating its great potentiality as high wear‐resistant material suitable for ocean environment.

show abstract

Fluorinated graphene: facile solution preparation and tailorable properties by fluorine-content tuning

Abstract: Fluorinated graphene with tuneable F-loading amount and properties was prepared via a facile solution approach using graphene oxide and liquid diethylaminosulfur trifluoride (DAST) as starting materials under mild conditions.

Cited by 146 publications

References 28 publications

Tuning the Reactivity of Graphene by Surface Phase Orientation

Tuning the Reactivity of Graphene by Surface Phase Orientation

Laser‐Induced Graphene in Controlled Atmospheres: From Superhydrophilic to Superhydrophobic Surfaces

High mechanical and tribological performance of polyimide nanocomposite reinforced by fluorinated graphene oxide

Contact Info

Product

Resources

About