Fluorination of petroleum oils in liquid phase with silver difluoride

Struve, W.; Benning, A.; Downing, F.; Lulek, R.; Wirth, Wolfjochen

doi:10.1021/ie50447a648

Cited by 12 publications

(3 citation statements)

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“…The strong fluorinating and oxidizing properties of AgF 2 were recognized early [4], but it was during and after the 2nd World War that reactivity of AgF 2 towards many materials was carefully tested [12]. Formation of AgF 2 ( Fig.…”

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confidence: 99%

Silverland: the Realm of Compounds of Divalent Silver—and Why They are Interesting

Grochala

2017

J Supercond Nov Magn

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In this personal account, the author takes readers on the journey to "Silverland," i.e., the emerging field of electronic and magnetic materials based on divalent silver (Ag 2+ ). He blends historical background with the reasons which led him to become involved in this research, as well as to proposing (with Roald Hoffmann, 2001) that high-T C superconductivity might ultimately be observed in doped Ag 2+ fluorides. More recent experimental and theoretical findings related to novel compounds, and their electronic and magnetic structure, are presented.

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confidence: 99%

Silverland: the Realm of Compounds of Divalent Silver—and Why They are Interesting

Grochala

2017

J Supercond Nov Magn

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“…were prepared by vapor phase fluorination of hydrocarbon oils with cobalt trifluoride. Fluorocarbon oils were also prepared by fluorination of naphthenic oils using silver difluoride as the fluorinating agent (191).…”

Section: Fluorinationmentioning

confidence: 99%

Halogenation

McBee¹

1948

Ind. Eng. Chem.

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“…Production methods and properties of compounds prepared in this period are given in several survey papers (1)(2)(3)(4)(5)(6)(7)(8). An electrochemical process developed by Simons(9-1ý, is capable of producing not only fluorocarbons but also perfluoro acids, amines, and ethers.…”

Section: Introductionmentioning

confidence: 99%