Fluorination of the silicon-terminated (100) diamond surface using C60F48

Schenk, Alex; Sear, Michael J.; Dontschuk, Nikolai; Tadich, Anton; Stacey, Alastair; Pakes, C. I.

doi:10.1016/j.diamond.2022.109084

Diamond and Related Materials

2022

DOI: 10.1016/j.diamond.2022.109084

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Fluorination of the silicon-terminated (100) diamond surface using C60F48

Alex Schenk

Michael J. Sear

Nikolai Dontschuk

et al.

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2024

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Cited by 3 publications

References 31 publications

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Formation of a Boron‐Oxide Termination for the (100) Diamond Surface

Schenk,

Griffin,

Tadich

et al. 2024

Adv Materials Inter

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A boron‐oxide termination of the diamond (100) surface has been formed by depositing molecular boron oxide B2O3 onto the hydrogen‐terminated (100) diamond surface under ultrahigh vacuum conditions and annealing to 950 °C. The resulting termination is highly oriented and chemically homogeneous, although further optimization is required to increase the surface coverage beyond the 0.4 monolayer coverage achieved here. This work demonstrates the possibility of using molecular deposition under ultrahigh vacuum conditions for complex surface engineering of the diamond surface, and may be a first step in an alternative approach to fabricating boron doped delta layers in diamond.

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Formation of a Boron‐Oxide Termination for the (100) Diamond Surface

Schenk,

Griffin,

Tadich

et al. 2024

Adv Materials Inter

View full text Add to dashboard Cite

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Synthesis, Surface Chemistry, and Applications of Non‐Zero‐Dimensional Diamond Nanostructures

Li,

Jiang,

Yang

2024

Small

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Diamond nanomaterials are renowned for their exceptional properties, which include the inherent attributes of bulk diamond. Additionally, they exhibit unique characteristics at the nanoscale, including high specific surface areas, tunable surface structure, and excellent biocompatibility. These multifaceted attributes have piqued the interest of researchers globally, leading to an extensive exploration of various diamond nanostructures in a myriad of applications. This review focuses on non‐zero‐dimensional (non‐0D) diamond nanostructures including diamond films and extended diamond nanostructures, such as diamond nanowires, nanoplatelets, and diamond foams. It delves into the fabrication, modification, and diverse applications of non‐0D diamond nanostructures. This review begins with a concise review of the preparation methods for different types of diamond films and extended nanostructures, followed by an exploration of the intricacies of surface termination and the process of immobilizing target moieties of interest. It then transitions into an exploration of the applications of diamond films and extended nanostructures in the fields of biomedicine and electrochemistry. In the concluding section, this article provides a forward‐looking perspective on the current state and future directions of diamond films and extended nanostructures research, offering insights into the opportunities and challenges that lie ahead in this exciting field.

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MoS₂ synthesis on fluorine-terminated Si substrates prepared by SF₆ mixed gas plasma

Ogino,

Kato,

Kito

2024

Jpn. J. Appl. Phys.

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MoS2 synthesis methods with fewer grain boundaries are expected for device applications. To control the nucleation density and to increase the domain size of MoS2 on Si substrate, MoS2 was synthesized on fluorine-terminated Si substrate prepared by SF6 mixed gas plasma. The average domain size of monolayer MoS2 synthesized on fluorine-terminated Si substrate was several times larger than that on pristine Si substrate, and grain boundaries were reduced. The MoS2 synthesized on the fluorine-terminated substrate was found to have improved crystallinity based on the results of Raman and photoluminescence spectroscopy. XPS analysis showed that no residual fluoride was observed on the substrate surface after CVD, suggesting that fluorine atoms were volatilized together with Mo by chemical reaction during CVD. fluorine-terminated surface prepared by SF6 mixed gas plasma contributes to increasing the domain size of MoS2, and it can be applied for selective growth in the subsequent CVD synthesis of MoS2.

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Fluorination of the silicon-terminated (100) diamond surface using C60F48

Cited by 3 publications

References 31 publications

Formation of a Boron‐Oxide Termination for the (100) Diamond Surface

Formation of a Boron‐Oxide Termination for the (100) Diamond Surface

Synthesis, Surface Chemistry, and Applications of Non‐Zero‐Dimensional Diamond Nanostructures

MoS₂ synthesis on fluorine-terminated Si substrates prepared by SF₆ mixed gas plasma

Contact Info

Product

Resources

About

Fluorination of the silicon-terminated (100) diamond surface using C60F48

Cited by 3 publications

References 31 publications

Formation of a Boron‐Oxide Termination for the (100) Diamond Surface

Formation of a Boron‐Oxide Termination for the (100) Diamond Surface

Synthesis, Surface Chemistry, and Applications of Non‐Zero‐Dimensional Diamond Nanostructures

MoS2 synthesis on fluorine-terminated Si substrates prepared by SF6 mixed gas plasma

Contact Info

Product

Resources

About

MoS₂ synthesis on fluorine-terminated Si substrates prepared by SF₆ mixed gas plasma