2022
DOI: 10.1007/s42114-022-00498-z
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Fluorine-induced surface modification to obtain stable and low energy loss zinc oxide/perovskite interface for photovoltaic application

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Cited by 24 publications
(9 citation statements)
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“…The evident shift of the Pb 4f 5/2 and 4f 7/2 signals to low binding energy for the ABSadded CsPbI 2 Br layer experimentally reveals the interaction of ABS with Pb in CsPbI 2 Br. [46][47][48] It is worth noting that there also exist two weak signals around 141.36 and 136.41 eV for the pristine CsPbI 2 Br layer, corresponding to the surface-uncoordinated Pb atoms (i.e., Pb 0 ). As a deep-level defect, Pb 0 leads to severe nonradiative recombination accordingly.…”
Section: Resultsmentioning
confidence: 99%
“…The evident shift of the Pb 4f 5/2 and 4f 7/2 signals to low binding energy for the ABSadded CsPbI 2 Br layer experimentally reveals the interaction of ABS with Pb in CsPbI 2 Br. [46][47][48] It is worth noting that there also exist two weak signals around 141.36 and 136.41 eV for the pristine CsPbI 2 Br layer, corresponding to the surface-uncoordinated Pb atoms (i.e., Pb 0 ). As a deep-level defect, Pb 0 leads to severe nonradiative recombination accordingly.…”
Section: Resultsmentioning
confidence: 99%
“…Photovoltaic devices are recognized as an innovative energy source. Current solar cell generations that utilize solution-based methods, such as organic, dye-sensitized, quantum dot, and perovskitebased technologies, [1][2][3][4] have made signicant advances in recent years compared to traditional silicon-and thin-lm-based solar cells. 5,6 Metal halide perovskite solar cells have been extensively studied, have shown considerable performance improvements, and are the subject of further commercial investigation.…”
Section: Introductionmentioning
confidence: 99%
“…55−57 Additionally, traditional passivation strategies usually have little effect on these oxygenrelated defects located on the surface of sp-SnO 2 . 58,59 Therefore, to improve the PCE of PSCs based on sp-SnO 2 , it is crucial to reduce the influence of these surface states on sp-SnO 2 on the devices. Herein, we propose an isolation strategy to reduce the interfacial recombination.…”
Section: ■ Introductionmentioning
confidence: 99%
“…sp-SnO 2 has complex surface states, such as oxygen-related defects due to the momentum exchange principle of the magnetron sputtering. These defect states act as SRH recombination sites, ultimately leading to non-radiative recombination at the interface. Additionally, traditional passivation strategies usually have little effect on these oxygen-related defects located on the surface of sp-SnO 2 . , Therefore, to improve the PCE of PSCs based on sp-SnO 2 , it is crucial to reduce the influence of these surface states on sp-SnO 2 on the devices.…”
Section: Introductionmentioning
confidence: 99%