Fluoro[imidobis(sulphuryl fluoride)]xenon. An example of a xenon–nitrogen bond

Abstract

The reaction of xenon difluoride with imidobis-(sulphuryl fluoride) in dichlorodifluoromethane at 0" yields the new compound, fluoro [imidobis(sulphuryl fluoride)]xenon, FXeN(SO,F),, the first example of xenon bonded to an element other than oxygen or fluorine under ordinary laboratory conditions.

Nature of the XeVI−N Bonds in F6XeNCCH3and F6Xe(NCCH3)2and the Stereochemical Activity of Their Xenon Valence Electron Lone Pairs

“…ÀNb onds occur for trigonal planar (sp 2 -hybridized) inorganic nitrogen ligandsd erived from the (FO 2 S) 2 N( imidobis(sulfurylfluoride)) group, that include FXeN(SO 2 F) 2 , [15][16][17] + , [19] the related (CF 3 O 2 S) 2 N( imidobis(sulfuryltrifluoromethyl)) group, which is solely represented by (Xe[N-(SO 2 CF 3 ) 2 ] 2 ), [20] and the sulfur-nitrogen-fluorine cations derived from NSF 3 ,n amely, [ F 4 S=NXe] + [21] and [F 4 S=NXe···NSF 3 ] + . [22] The only examples in which xenon is bonded to sp 3 -hybridized nitrogen are [F 5 Te N(H)Xe]…”

Synthesis of 3,6-dioxa-Δ7-4-trifluoromethyl perfluorooctyl trifluoromethyl sulfonimide: bis[(perfluoroalkyl)sulfonyl] superacid monomer and polymer

“…The polymers which were developed are known as perfluorosulfonimide ionomers or PFSI (Fig. 1) and evolved from small molecule work on perfluoroalkylsulfonyl derivatives to form carbon and nitrogen xenon bonds [15,16]. Beginning in the late 1970s, numerous Brfnsted nitrogen superacids were synthesized and are known as bis((perfluoroalkyl)sulfonyl)imides [17].…”

Neutral rare-gas containing charge-transfer molecules in solid matrices. III. HXeCN, HXeNC, and HKrCN in Kr and Xe

“…The first xenon-nitrogen bond in FXeN͑SO 2 F͒ 2 was reported in 1974 by DesMarteau and LeBlond and up to date this and a few similar compounds seem to be the only examples of Xe-N bonding. [3][4][5][6] In 1979, Turbini et al 7 reported the synthesis of Xe͑CF 3 ͒ 2 with a xenon-carbon bond but its unequivocal spectroscopic characterization is still lacking. During the last few years, a number of compounds with Xe-C bonds have been synthesized and characterized, including ionic compounds (C 6 F 5 Xe) ϩ (C 6 F 5 BF 3 )…”