Fluoroaldehyde polymers

Neeld, K.; Vogl, Otto

doi:10.1002/pol.1981.230160101

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Cited by 12 publications

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“…Trifluoroacetaldehyde (fluoral) polymerization has been studied in the past. 18,19 Fluoral was shown to polymerize to a stereospecific crystalline, isotactic polymer or to a less stereospecific, amorphous polymer. It was found that fluoral has the highest ceiling temperature of all the perhaloacetaldehydes.…”

Section: Introductionmentioning

confidence: 99%

Haloaldehyde polymers. 47. Analysis of linear fluoral oligomers by gas chromatography and potassium ionization of desorbed species

Simonsick¹,

Hatäda²,

Xi³

et al. 1990

Macromolecules

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Linear fluoral oligomers initiated with tert-butoxide or bornyl oxide and acetate end-capped were analyzed by potassium ionization of desorbed species (K+IDS) combined with gas chromatography (GC). Using K+IDS it was possible to identify fluoral diacetate and the oligomers up to the undecamer. tert-Butoxide initiated oligomers showed masses from the unimers of 253 daltons up to the mass of 1233 daltons, the undecamer. The individual lower oligomers were also identified by GC. Bornyl oxide terminated, acetate capped fluoral oligomers were also analyzed and characterized to masses up to 1215 daltons, the decamer, by K+IDS; GC characterization was also carried out.

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Section: Introductionmentioning

confidence: 99%