Fluoroaromatic Compounds

Fürin, G. G.; GREBENSHCHIKOVA, G. F.; L'vova, A. Ya.; Vlasov, V. M.; Yakobson, G. G.

doi:10.1007/978-3-642-70207-5_3

Cited by 5 publications

(2 citation statements)

References 166 publications

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“…Decafluorodiphenyl is used as initial reagent for producing octafluorobenzidine 21 , a monomer used for polymer synthesis 22 , particularly fluorinated polyimide 23 films. Aromatic polyimides have been paid great attention in the microelectronics as interlayer dielectrics due to their properties, including high thermal stability, chemical resistance and good mechanical and electrical properties.…”

Section: Resultsmentioning

confidence: 99%

Ullmann Reaction Optimization within Bitolyl and Decafluorobiphenyl Synthesis

Колотаев¹,

Razinov²,

Khachatryan³

2018

Orient. J. Chem

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Section: Resultsmentioning

confidence: 99%

Ullmann Reaction Optimization within Bitolyl and Decafluorobiphenyl Synthesis

Колотаев¹,

Razinov²,

Khachatryan³

2018

Orient. J. Chem

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“…Remarkably, organic molecules based on both imidazole and polyfluoroaryl scaffolds show antihypertensive ( I ), , neuroprotective ( II ), , and antimicrobial effects ( III ) and also find practical applications in materials science ( IV ), for instance, as functional elements for solar cells (Figure ). At the same time, one cannot omit possible negative effects of polyfluoroorganics on both the environment and human health …”

Section: Introductionmentioning

confidence: 99%

Transition-Metal-Free C–H/C–Li Coupling of Nonaromatic 2H-Imidazole 1-Oxides with Pentafluorophenyl Lithium in the Design of Novel Fluorophores with Intramolecular Charge Transfer Effect

et al. 2020

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Methodology of nucleophilic substitution of hydrogen (SN H) was first applied for the direct modification of nonaromatic 2H-imidazoles to afford novel polyfluoroarylated azaheterocycles. Scope, tolerance for these transition-metal-free C–H/C–Li coupling reactions, and photophysical properties for the novel 4-(perfluorophenyl)-5-aryl-2H-imidazoles were comprehensively studied. In particular, some of the obtained perfluoroaryl-substituted 2H-imidazoles were found to be of particular interest as promising push–pull fluorophore systems in the design of fluorometric sensor materials due to the effect of intramolecular charge transfer.

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Fluorinated Aromatic Compounds

Boudakian¹

2000

Kirk-Othmer Encyclopedia of Chemical Technology

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This article covers the preparation, properties, reactions, and applications of three types of fluorinated aromatic compounds: ring‐fluorinated aromatics, side‐chain fluorinated aromatics and arylfluoroalkyl ethers, and fluorinated nitrogen heterocyclics. The special properties conferred by fluorine justify the higher costs required to produce fluoroaromatics. Depending on which substituents are present, fluoroaromatic intermediates can be converted into fluorinated or fluorine‐free commercial end products. Fluorine‐containing aromatics have been incorporated into drugs (hypnotics, tranquilizers, antiinflammatory agents, analgesics, antibacterials) and into crop‐protection chemicals (herbicides, insecticides, fungicides). Liquid crystals, positron emission tomography, and imaging systems represent new areas where fluoroaromatics and fluoroheterocyclics have gained attention. For fluorine‐free end products, the lability of fluorine in fluoronitrobenzenes and other activated molecules permit it to serve as a handle in hair dye manufacturing operations, high performance polymers (eg, PEEK), drugs (eg, diuretics), fiber‐reactive dyes, analytical applications, and biological diagnostic reagents.

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Fluoroaromatic Compounds

Cited by 5 publications

References 166 publications

Ullmann Reaction Optimization within Bitolyl and Decafluorobiphenyl Synthesis

Ullmann Reaction Optimization within Bitolyl and Decafluorobiphenyl Synthesis

Transition-Metal-Free C–H/C–Li Coupling of Nonaromatic 2H-Imidazole 1-Oxides with Pentafluorophenyl Lithium in the Design of Novel Fluorophores with Intramolecular Charge Transfer Effect

Fluorinated Aromatic Compounds

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