1958
DOI: 10.1021/ja01547a030
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Fluorocarbon Nitrogen Compounds. III.1 Some Reactions of Bis-(trifluoromethyl)-amine, (CF3)2NH2

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Cited by 49 publications
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“…Few of these organic salts have been used in metatheses [49–52] or for the synthesis of organic molecules with the N(CF 3 ) 2 group [39–40,53–54] . So far, mercury complexes, for example [Hg{N(CF 3 ) 2 } 2 ], are the sole stable metal complexes with the N(CF 3 ) 2 ligand, known [55] . The salts M {N(CF 3 ) 2 } ⋅ NCCH 3 ( M =Ag, Cu) have been described as white solids [49] .…”
Section: Figurementioning
confidence: 99%
See 1 more Smart Citation
“…Few of these organic salts have been used in metatheses [49–52] or for the synthesis of organic molecules with the N(CF 3 ) 2 group [39–40,53–54] . So far, mercury complexes, for example [Hg{N(CF 3 ) 2 } 2 ], are the sole stable metal complexes with the N(CF 3 ) 2 ligand, known [55] . The salts M {N(CF 3 ) 2 } ⋅ NCCH 3 ( M =Ag, Cu) have been described as white solids [49] .…”
Section: Figurementioning
confidence: 99%
“…[ 39 , 40 , 53 , 54 ] So far, mercury complexes, for example [Hg{N(CF 3 ) 2 } 2 ], are the sole stable metal complexes with the N(CF 3 ) 2 ligand, known. [55] The salts M {N(CF 3 ) 2 } ⋅ NCCH 3 ( M =Ag, Cu) have been described as white solids. [49] However, these salts cannot be stored because they immediately start to decompose, even at low temperature.…”
mentioning
confidence: 99%
“…In addition to the usual 4 benzene protons, the n.m.r. spectrum showed 2 methine hydrogens at 7.30, 6 protons at 8.64 (2 methyl groups), 6 protons at 8.74 (2 methyl groups), 3 protons at r 8.99 (1 methyl group), and 3 protons at 9.27 (1 methyl group).…”
Section: Cho Cho /Oh XIII Xivmentioning
confidence: 99%
“…(5) G. F. Hennion and T. F. Banigan, Jr., ibid., 68, 1202 (1946). (6) For leading references, see E. M. Arnett, J. Org. Chem., 25, 324 (1960); also, M. S. Newman and G. R. Kahle, ibid., 23, 666 (1958).…”
mentioning
confidence: 99%
“…The borane coordination chemistry and Lewis basicity of the phosphorus and nitrogen atoms in aminophosphines have been studied extensively,1'19 with experimental results suggesting that the phosphorus atom is the more basic site. For example, in the reactions of B2H6 with acyclic aminophosphines of the type (Me2N)"PMe3_",14-17,19 Me2NPF2,9 (Me2N)2PF,9 Me2NPBu2,18 (1) Cowley, A. H.; Dewar, M. J. S.; Jackson, W. R.; Jennings, W. B. J. Am.…”
Section: Introductionmentioning
confidence: 99%