Applying a concrete surface treatment method (epoxy or primer) can prevent water from penetrating concrete through surface pores. However, if the concrete surface is damaged, the subsequent reconstruction can be expensive and time-consuming. Concrete that is resistant to internal and external water has been extensively developed and used to supplement the surface treatment method. Herein, we prepared specimens by mixing cement mortar with fatty-acid-salt-based calcium stearate attached to two natural pozzolanic materials—diatomite and yellow clay. The physical tests measured (1) the air content, (2) flow test, (3) compressive strength, and (4) activity Factor. Durability experiments were performed on (1) the contact angle, (2) chloride ion diffusion coefficient, and (3) water absorption test. The results revealed that the compressive strength of concrete decreased as the calcium stearate content increased. Furthermore, it was confirmed that the contact angle of the test piece using the pozzolanic substance and calcium stearate was twice as high. It was confirmed that the sand test specimen had the highest water absorption rate, and the DT3% had the lowest. (Sand%: 11.8 > OPC: 6.5 > DT3%: 2.4), the chloride diffusion coefficient also showed similar results. (Sand%: 12.5 > OPC: 8.4 > DT1%: 8.8)Due to its unique insolubility, calcium stearate retards hydrate formation when mixed alone and negates compressive strength loss when combined with pozzolanic mixtures rich in SiO2 and Al2O3. Furthermore, the ideal method for producing water-resistant cement mortar is to evenly disperse calcium stearate in the porous powder of cement mortar.