Two-dimensional transition
metal carbides (MXenes) are of great
interest as electrode materials for a variety of applications, including
solar cells, due to their tunable optoelectronic properties, high
metallic conductivity, and attractive solution processability. However,
thus far, MXene electrodes have only been exploited for lab-scale
device applications. Here, to demonstrate the potential of MXene electrodes
at an industry-relevant level, we implemented a scalable spray coating
technique to deposit highly conductive (
ca
. 8000
S/cm, at a
ca
. 55 nm thickness) Ti
3
C
2
T
x
films (
T
x
: surface functional groups,
i
.
e
., −OH, −O, −F)
via
an automated spray system. We employed these Ti
3
C
2
T
x
films as rear electrodes for silicon heterojunction solar cells
as a proof of concept. The spray-deposited MXene flakes have formed
a conformal coating on top of the indium tin oxide (ITO)-coated random
pyramidal textured silicon wafers, leading to >20% power conversion
efficiency (PCE) over both medium-sized (4.2 cm
2
) and large
(243 cm
2
,
i
.
e
., industry-sized
6 in. pseudosquare wafers) cell areas. Notably, the Ti
3
C
2
T
x
-rear-contacted
devices have retained around 99% of their initial PCE for more than
600 days of ambient air storage. Their performance is comparable with
state-of-the-art solar cells contacted with sputtered silver electrodes.
Our findings demonstrate the high-throughput potential of spray-coated
MXene-based electrodes for solar cells in addition to a wider variety
of electronic device applications.