Force Constants, Mean Amplitudes of Vibration, Shrinkage Effects, Coriolis Constants, and Thermodynamic Functions of Vanadium Pentafluoride.

Vizi, B.; Brünvoll, J.; Müller, A.; Schwieter, Ulrich; Paasiv́irta, Jaakko

doi:10.3891/acta.chem.scand.22-1279

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“…This is the case of the triangular bipyramidal PF 5 , AsF 5 , and VF 5 molecules. The mean amplitudes of vibration for them are, as expected, slightly lower than those of the respective hexafluoroanions (i.e., 0.0448Å for the axial P-F and 0.0406Å for the equatorial P-F bonds in PF 5 [11]; 0.0410Å and 0.0386Å for the same bonds in AsF 5 [11] and 0.0415Å and 0.0405Å for the corresponding bonds in VF 5 [12] (all values at 298 K)), confirming the somewhat stronger bonds for the neutral XF 5 species.…”

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confidence: 62%