Cu 46 Zr 47−x Al 7 M x (M = Ce, Pr, Tb, and Gd) bulk metallic glassy (BMG) alloys were prepared by copper-mold vacuum suction casting. The effects of rare-earth elements on the glass-forming ability (GFA), thermal stability, and mechanical properties of Cu 46 Zr 47−x Al 7 M x were investigated. The GFA of Cu 46 Zr 47−x Al 7 M x (M = Ce, Pr) alloys is dependent on the content of Ce and Pr, and the optimal content is 4 at.%. Cu 46 Zr 47−x Al 7 Tb x (x = 2, 4, and 5) amorphous alloys with a diameter of 5 mm can be prepared. The GFA of Cu 46 Zr 47−x Al 7 Gd x (x = 2, 4, and 5) increases with increasing Gd. T x and T p of all decrease. T g is dependent on the rare-earth element and its content. ΔT x for most of these alloys decreases except the Cu 46 Zr 42 Al 7 Gd 5 alloy. The activation energies ΔE g , ΔE x , and ΔE p for the Cu 46 Zr 42 Al 7 Gd 5 BMG alloy with Kissinger equations are 340.7, 211.3, and 211.3 kJ/mol, respectively. These values with Ozawa equations are 334.8, 210.3, and 210.3 kJ/mol, respectively. The Cu 46 Zr 45 Al 7 Tb 2 alloy presents the highest microhardness, Hv 590, while the Cu 46 Zr 43 Al 7 Pr 4 alloy presents the least, Hv 479. The compressive strength (σ c.f. ) of the Cu 46 Zr 43 Al 7 Gd 4 BMG alloy is higher than that of the Cu 46 Zr 43 Al 7 Tb 4 BMG alloy.