Formation of Covalent Bonds from Platinum or Palladium to Carbon by Direct Substitution

Redox-Induced Aromatic C–H Bond Functionalization in Metal Complex Catalysis from the Electrochemical Point of View

“…The ability of Pd(II) to activate C-H bonds through chelation-assisted processes has been known since the 1960s. Nitrogen-containing directing groups were found to promote the insertion of palladium into an ortho-C-H bond, which led to the formation of stable and isolable cyclopalladated complexes from Pd(II) starting material (Scheme 6) [25,[31][32][33][34][35][36][37][38][39][40]. Despite the large literature devoted to the synthesis of various palladacycles and studies of their reactivity, their redox properties, which are necessary to describe and understand the mechanisms of catalytic reactions involving them, are elucidated only in few works [11,15,24,25,[41][42][43][44].…”

“…The ability of Pd(II) to activate C-H bonds through chelation-assisted processes has been known since the 1960s. Nitrogen-containing directing groups were found to promote the insertion of palladium into an ortho-C-H bond, which led to the formation of stable and isolable cyclopalladated complexes from Pd(II) starting material (Scheme 6) [25,[31][32][33][34][35][36][37][38][39][40]. The ability of Pd(II) to activate C-H bonds through chelation-assisted processes has been known since the 1960s.…”

Crystal structure of (5-bromo-2-pyridyl)ferrocene, C15H12BrFeN

“…Palladacycles containing aP d-C bond intramolecularly stabilized by one donor atom were first reported in the middle 1960s [1]. Fortyyears later, palladacycles are one of themost developed and studied classes of precatalysts because of their structural versatility and high catalytic activity [2,3].…”

Structures, Redox and Spectroscopic Properties of PdII and PtII Complexes Containing an Azo Functionality

“…[3] The authors express their regret for any inconvenience that might have arisen, and apologise to the original authors and the editors of Eur. J. Inorg.…”