2010
DOI: 10.1103/physrevb.82.184205
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Formation ofα-MnandRstructures from theβ-Mnstructure in Mn-Si alloys

Abstract: The Mn-Si alloy system undergoes the ͑␤-Mn→ ␣-Mn+ R͒ eutectoid reaction at 908 K around 8 at. % Si. The crystal structures of the ␤-Mn, ␣-Mn, and R phases were reported to consist of complex coordination polyhedra such as a polyhedron with coordination number ͑CN͒ 12: that is, an icosahedral atomic cluster. The notable features of these structures are that both the ␣-Mn and R structures are characterized by arrays of penetrated CN16 pairs while penetrated CN14 pairs are present in the ␤-Mn structure. In a pene… Show more

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