The aim of the work is the theoretical substantiation of the mechanism of water structuring using the effect of hydrophobic hydration on the example of the use of carbohydrate as a nanomodifier. To achieve the goal, the following tasks were set: to perform experimental and theoretical studies of the mechanism of influence of colloidal hydrophobic surfactants on the structure of water. The paper presents the results of theoretical studies of the influence of colloidal hydrophobic surfactants on the structure of water and the hydration mechanism of slag Portland cement. It is shown that the introduction of these surface-active substances into water in very low concentrations leads to the effect of hydrophobic hydration, that is, changes in the interaction between water molecules. Hydrophobic hydration contributes to the formation of the pore structure. It was established that hydrophobic hydration is characterized by the fact that part of the dissolved substance inhibits the translational movement of water molecules and is due to the fact that part of the solution space, corresponding to the own volume of the particles of the dissolved substance, is inaccessible to water molecules. Hydrophilic and hydrophobic hydration have different mechanisms. Large hydrophobic ions cause ordering of the water structure. Having a more ordered structure than pure water, solutions of these salts require less work for dissolution, as a result of which the solubility of the latter increases. The conducted experiments allow us to draw an unequivocal conclusion that polar groups are unable to prevent hydrophobic hydration. The introduction of hydrophobic surfactant molecules into water in the form of dimers is the structuring of water, that is, the formation of a continuous fractal network of water molecules.
Keywords: fine-grained concrete, slag Portland cement, hydration, modification, surfactants, water activation