The photocatalytic decomposition of acetaldehyde in air at initial concentrations ranging from 3 to 200 mg m À3 has been studied in a semitransparent closed box with an inlet volume of 0.056 m 3 . The photocatalytic reactors consisted of a glass tube, 250 mm long with inside diameters of 28, 35, or 45 mm, whose inner surface was coated with a thin ®lm of titanium dioxide, and a 6-W blacklight uorescent lamp located at the axis of the glass tube. The decomposition of acetaldehyde was almost complete within 1±3 h and its main product was carbon dioxide. A kinetic study showed that the photocatalytic reaction obeys a Langmuir adsorption isotherm. Although the light intensity was certainly decreased with the distance from the light source, the degree of this decrease was much smaller than the degree of the decrease in the kinetic constants, which suggests that the light intensity is not simply proportional to the degree of the photo-excitation of TiO 2 and the rate of the resulting photocatalytic decomposition of acetaldehyde. # 1999 Society of Chemical Industry Keywords: photocatalytic reaction; acetaldehyde; titanium dioxide; photocatalytic reactor; batch recirculation systemVolume of a box (m 3 )
INTRODUCTIONIn highly airtight houses that have little ventilation in order to save on the amount of energy required to maintain the room temperature almost constant throughout the year, various kinds of volatile organic compounds are released from the adhesives and preservatives used in house-building materials or from furniture. These compounds then accumulate in increasing amounts in the airtight room, which leads, in turn, to the discomfort of the inhabitant and to health-related complaints.