For bifacial Cu(In,Ga)Se 2 solar cells with submicron absorber thickness, an Al 2 O 3 -layer deposited by a simple, self-organized spray-pyrolysis process onto the transparent SnO 2 :F back-contact is used to increase open circuit voltage and thereby increase power conversion efficiency, especially for rear-illumination, indicating reduced charge carrier back-contact recombination. On non-passivated SnO 2 :F, a thin (10nm) Mo-layer improved the electrical back-contact properties, while on Al 2 O 3 -passivated SnO 2 :F, the solar cell performance was higher without Mo-modification. However, even with Momodification, the solar cell performance increased for Al 2 O 3 -passivated compared to non-passivated back-contacts demonstrating the benefit of the Al 2 O 3 -layer for bifacial solar cells with submicron Cu(In,Ga)Se 2 absorber layers.