Formation of Various Bicolor Fluorescent Micropatterns on a Single Polymer Film Based on Concurrent Photobleaching and Photobase Generation

Abstract

Various bicolored fluorescent micropatterns are fabricated on a single polymer film by concurrent photobleaching and a photobase generation process. A polymer, bearing anthracene and oxime-urethane groups, is dyed with rhodamine B isothiocyanate after irradiation with 310-nm UV light. The photochemical reaction of the polymer is monitored by UV, IR absorption, and fluorescence emission spectroscopy. Differently colored fluorescent micropatterns are obtained by selectively exciting each dye moiety. Various bicolored fluorescent micropatterns are observed through varying the excitation wavelength and observation wavelength ranges using a confocal microscope. This bicolored fluorescence patterning method will be useful to apply in photonic/electronic devices.

Oxime–Urethane Structure‐Based Dynamically Crosslinked Polyurethane with Robust Reprocessing Properties

“…Meanwhile, DOPU-3 is also expected to be used as a photoalkaliproducing agent for photocuring. [42,43]…”