Formation of α-ketols in the reduction of 1,3-diketones under clemmensen conditions

Chuang, V. T.; Scott, Robert B.

doi:10.1039/c29690000758

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B 12-cyclopropanediols1

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1970

1974

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“…Chuang and Scott have also reported isolation of an -ketol under Clemmensen conditions. 44 Curphey and his group continued their work on the behavior of 1,3-diketones by studying the electrochemical reduction of 2-methyl-2-acetylcyclohexanone,45 the system studied by Wenkert and Kariv under Clemmensen conditions. The anions of the expected epimeric cyclopropanediols were trapped as the diacetates by using acetic anhydride.…”

Section: B 12-cyclopropanediolsmentioning

confidence: 99%