Encyclopedia of Reagents for Organic Synthesis
DOI: 10.1002/047084289x.rf025.pub2
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Formic Acid

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“…p K a HI = −9.5 30 vs . p K a FA = 3.77), 31 which would require the convergence of two HI units. This observation is consistent with our experimental findings on chemoselectivity.…”
mentioning
confidence: 99%
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“…p K a HI = −9.5 30 vs . p K a FA = 3.77), 31 which would require the convergence of two HI units. This observation is consistent with our experimental findings on chemoselectivity.…”
mentioning
confidence: 99%
“…The first scenario was deemed unlikely based on the thermodynamically unfavorable equilibrium between FA and iodide (cf. pK a HI = −9.5 30 vs. pK a FA = 3.77), 31 which would require the convergence of two HI units. This observation is consistent with our experimental findings on chemoselectivity.…”
mentioning
confidence: 99%