Cetyltrimethylammonium bromide (CTAB) surfactant was
proven to
be a reliable emulsifier for creating stable emulsions used for drilling,
well stimulation, and EOR. The presence of acids like HCl during such
operations may lead to the formation of acidic emulsions. No previous
comprehensive investigations have been done to study the performance
of CTAB-based acidic emulsions. This paper, therefore, presents experimental
investigations of the stability, rheological behavior, and pH responsiveness
of a CTAB/HCl-based acidic emulsion. The effects of temperature, pH,
and CTAB concentration on the emulsion stability and rheology have
been investigated using a bottle test and a TA Instrument DHR1 rheometer.
Viscosity and flow sweep were analyzed for the steady state at a shear
range of 2.5–250 s–1. For the dynamic tests,
the storage modulus (G′) and loss modulus
(G″) were observed by applying the oscillation
test at the range of shear frequency from 0.1 to 100 rad/s. The results
revealed that the emulsion exhibits steady rheological behaviors ranging
from Newtonian to shear-dependent (psedosteady), depending on the
temperature and CTAB concentration. The tendency of the emulsion to
exhibit a solid-like behavior is also dependent on CTAB concentration,
temperature, and pH. However, the pH responsiveness of the emulsion
is more significantly observed within the acidic range of the pH.