A technology for production of nano glass ceramic materials based on aluminosilicate glass doped with chromium oxide is proposed. A comparative study of the spectral luminescence properties of for sterite glass ceramics and single crystal doped with chromium ions is performed. It is shown that chromium ions are partially incorporated into the glass ceramics crystalline phase. The quantum luminescence yields of Cr 4+ ions in forsterite nano glass ceramics and single crystal are found to be close.