Some
silicon-rich mineral additives are known to be capable of
capturing volatile elements evolved during combustion and, thus, may
be used to mitigate ash-related problems (e.g., particulate matter
emissions, fouling/slagging, and corrosion). Considering that silicon
is also rich in some biomasses (e.g., rice husk), this work aims to
explore how co-firing various silicon-rich biomasses with coal would
affect fine ash formation and slagging deposition. Combustion experiments
of individual biomasses, a low-rank coal, and their blends were conducted
on a drop-tube furnace in simulated air and at 1300 °C. The fine
ash was collected by a Dekati low-pressure impactor, and the high-temperature
slags were collected by uncooled mullite tubes. The particle size
distributions of fine ash were obtained. The morphology and composition
of fly ash and the slags were carefully characterized by a scanning
electron microscope equipped with an energy-dispersive spectrometer.
The results indicate that the particle size distributions of particulate
matter whose aerodynamic diameter is less than 10 μm (PM10) from combustion of all of the fuels are similarly bimodal.
The ash-based yields of particulate matter whose aerodynamic diameter
is less than 1 μm (PM1) and particulate matter whose
aerodynamic diameter is between 1 and 10 μm (PM1–10) from individual fuels decrease in the order: coal ≫ corn
stalk > bagasse > rice husk. Interactions between biomass and
coal
promote the release of alkali chlorides while inhibit the vaporization
of Ca, Mg, and Fe from the coal during co-combustion. For the rice
husk and bagasse with a relatively low content of K, the emission
of PM1 during co-combustion is suppressed. However, for
the corn stalk with a high content of K, the emission of PM1 from co-combustion is promoted evidently. The rice husk ash shows
a weak tendency of slagging, while the corn stalk shows a serious
tendency of slagging. The slagging tendency of bagasse ash is between
that of rice husk and corn stalk ashes. During co-combustion of silicon-rich
biomass and coal, the interactions between Si and Mg/Ca are favored,
while those between Si and Na/K are suppressed. These result in more
Mg and Ca in the coarse particles. Therefore, the ash slagging tendency
in co-combustion is generally reduced.