Fouling-Resistant Behavior of Hydrophobic Surfaces Based on Poly(dimethylsiloxane) Modified by Green rGO@ZnO Nanocomposites

Abstract

In line with global goals to solve marine biofouling challenges, this study proposes an approach to developing a green synthesis inspired by natural resources for fouling-resistant behavior. A hybrid antifouling/foul release (HAF) coating based on poly(dimethylsiloxane) containing a green synthesized nanocomposite was developed as an environmentally friendly strategy. The nanocomposites based on graphene oxide (GO) and using marine sources, leaves, and stems of mangroves (Avicennia marina), brown algae (Polycladia myrica), and zinc oxide were compared. The effectiveness of this strategy was checked first in the laboratory and then in natural seawater. The performance stability of the coatings after immersion in natural seawater was also evaluated. With the lowest antifouling (17.95 ± 0.7%) and the highest defouling (51.2 ± 0.9%), the best fouling-resistant performance was for the coatings containing graphene oxide reduced with A. marina stem/zinc oxide (PrGZS) and graphene oxide reduced with A. marina leaves/zinc oxide with 50% multiwall carbon nanotubes (PrGZHC50), respectively. Therefore, the HAF coatings can be considered as developed and eco-friendly HAF coatings for the maritime industry.