Four-coordinate and pseudo five-coordinate Hg(II) complexes of a new bidentate phosphorus ylide: X-ray crystal structure and spectral characterization

Four-coordinate Pd(II) complexes containing non-symmetric phosphorus ylides: Synthesis, characterization, and catalytic behavior towards Suzuki reaction

“…In the 31 P NMR spectra the signal due to PCH appears as a broad signal for 2 and doublets for 1 and 3e5. The significant downfield shift of these signals from that of the free ylides are in agreement with the C-bonding of the ylides [43,45]. The coordination via the phosphine moiety is also clearly evidenced from the strong downfield shifts of the signals due to PPh 2 group when compared to that of the same signal in the free ylides [4,11].…”

Synthesis, characterization and theoretical and fluorescence emission microscopy studies of new Pd/Pt–cyclopropa[60]fullerene complexes: Application of Taguchi method for optimization of parameters in Suzuki–Miyaura reaction

“…C 60 (+99.5%) and M(dba) 2 (M = Pd or Pt; dba = dibenzylideneacetone) were obtained from commercial sources and used without further purification. Phosphorus ylides Y 1 and Y 2 were synthesized and characterized as previously reported . Toluene and n ‐hexane were used as reagent grade and dried over Na/benzophenone.…”

Synthesis and Characterisation of Hg(II) Complexes Including Bidentate Phosphorus Ylides

“…) and the complexes [(3) HgX 2 ] (X=Cl(11), Br(12), I(13)) and [(4) HgX 2 ] (X=Cl(14), Br(15), I (16)) were prepared based on the published methods [50][51][52]. Synthesis of [(1) HgCl 2 ] (5); general procedure for Hg(II) halide complexes A solution of 1 (0.2 g, 0.34 mmol) in the same solvent (5 mL) was added dropwise to a solution of HgCl 2 (0.092 g, 0.34 mmol) in methanol (5 mL), at -5 °C and stirred for 2 h. The separated solid was filtered, washed with ice-cold methanol and dried in vacuo.…”